App source of IP sent?

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I have a suspicious IP transmission from my computer each time I start up.
I use Wallwatcher to monitor traffic on my Linksys DSL router and can see
this activity and ID the location.  but what application on my computer is
making the request?.

How can I trace the source application that made the request for a
particular IP output?

I my case its something from WilTel Communications group 6

Any thoughts appreciated.

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